COMMON OCCURRENCES OF AUTHIGENIC PYRITE CRYSTALS IN CRETACEOUS OIL SANDS AS CONSEQUENCE OF BIODEGRADATION PROCESSES
ABSTRACT
COMMON OCCURRENCES OF AUTHIGENIC PYRITE CRYSTALS IN CRETACEOUS OIL SANDS AS CONSEQUENCE OF BIODEGRADATION PROCESSES
Journal: Geological Behavior (GBR)
Author: Timothy Bata, Nuhu K. Samaila, A.S. Maigari, M. B. Abubakar & Simon Y. Ikyoive
This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited
DOI: 10.26480/gbr.02.2017.26.30
Ten (10) Cretaceous oil sands from different localities around the world were studied with the aim of reporting the common occurrence of authigenic pyrite crystals in them. The observed pyrite crystals (both framboid and euhedral) are restricted to the pore spaces of the studied oil sands, in close association with biodegraded oils and other authigenic minerals. Diagenetic processes in one of the studied samples triggered the transformation of framboidal pyrite crystals to octahedral pyrite crystals. This study demonstrates that geological conditions/processes that lead to the formation of authigenic pyrite crystals in sandstones are those that favour biodegradation. Potentially, these conditions include occurrence at shallow depths (< 2000 m), moderate reservoir temperatures that can support microbial life (temperature < 80° C), availability of micro-organisms that are capable of degrading oils in the reservoir, nutrient availability (e.g., iron, nitrogen, potassium, and phosphorus), and oil volume in the reservoir. Studied framboidal pyrite crystals were observed to occur within confined spaces. The oils (organic matter) associated with the studied samples are believed to have played an important role of providing the source of spherule moulds for framboid pseudomorphs and aided the stabilization of the gel in which the framboid crystals were protected. TIC fragmentograms of the saturate fractions of the oils extracted from the studied oil sands show progressive depletion of chromatographically resolved hydrocarbons (e.g. n-alkanes, acyclic isoprenoid alkanes; alkyl benzenes, naphthalenes and phenanthrenes) relative to the unresolved hydrocarbon mixture, forming unresolved complex mixture (UCM) humps, consistent with oils that have undergone biodegradation.| Pages | 26-30 |
| Year | 2017 |
| Issue | 2 |
| Volume | 1 |


Sabah experienced moderate seismicity in the active fault zones located in Kundasang, Ranau of 6.0 MW within minor damage recorded at Sabah recently. The damage following the earthquake and more than 100 aftershocks affected 61 buildings such as schools, hospital and mosque, 22 roads and 22 slopes. Over the past 114 years, a total of 124 with magnitudes ranging from 2.9 to 6.0 are known to have occurred. The earthquake in Sabah that struck Ranau, carrying a moment magnitude of 6.0 on 5 June recently lasted for 30 seconds. This earthquake was the strongest to affect Malaysia since 1976 in Lahad Datu. The latest thesis in the Sabah region had been carried out in Kundasang, Kudat and two buildings in KK city. The objective was to presents the evaluation of soil sample taken in Kota Kinabalu (KK) city that could possibly subjected to low intensity earthquake effects. The evaluation of determination of the soil amplification factor is used to determine the influence of soil condition on buildings in KK city. With the input motion of Whittier Narrows (6.0 Mw, ts = 0.005 s) and KKM Ranau (5.9 Mw, ts = 0.01 s), the analysis of the maximum acceleration for PGA and PSA will be varies with the use on program of NERA and DEEPSOIL V5.1. From the appendixes as shown in appendix, it is known that most of their soils are consisting of a surface alluvium layer varying the thickness in between of approximately 5 m and 20 m in refer to some researcher. Most of the soil condition is reviewed that there are soil type of B, C, D and E in according to (Technical Committe B/525, 2005). This study shows that the soil amplification factors for each location in KK city are various with the input motion of 5.9 Mw, ts = 0.01 s and 6.0 Mw, ts = 0.005 s.
